リチウム炎色反応
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深紅色の炎でリチウムを同定する
目的
リチウムイオンが生じる特徴的な深紅色の炎色を観察し、他のアルカリ金属の炎色反応と比較する。
背景
Lithium produces a distinctive crimson-red flame when heated. The emission occurs primarily at 670.8 nm as the excited 2s electron returns to the ground state. Lithium compounds were historically used to produce red colors in fireworks before the introduction of strontium-based alternatives.
安全上の警告
- Wear safety goggles at all times
- Keep hair tied back near open flames
- Handle HCl with care
必要なPPE
材料
-
Lithium chloride (LiCl) (1 g)
-
Hydrochloric acid (HCl) (10 mL)1M concentration
-
Distilled water (50 mL)For cleaning
器具
手順
Clean the nichrome wire by dipping in HCl and heating until no color is visible in the flame.
Place a small amount of lithium chloride on the watch glass.
Dip the clean wire into HCl, then touch it to the lithium chloride sample.
Hold the wire in the Bunsen burner flame and observe the characteristic crimson-red color.
Record observations and compare with the sodium flame test if already performed.
予想される結果
A bright crimson-red flame should appear. The color is distinct from the red produced by strontium (which is more scarlet) and potassium (which is lilac/violet).
後片付け
Clean the wire loop with HCl. Dispose of chemicals per lab protocol.
詳細
- カテゴリ
- Flame Tests
- 難易度
- Beginner (Middle School)
- 所要時間
- 15 分
- 推定費用
- $8.00
- ステップ数
- 5
- 材料
- 3