カリウム炎色反応
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ライラック/紫色の炎でカリウムを同定する
目的
カリウムイオンが生じるライラック/紫色の炎色を観察し、コバルトブルーガラスを使ってナトリウム汚染と区別する方法を学ぶ。
背景
Potassium produces a pale lilac or violet flame when heated. The emission occurs at 766.5 nm and 769.9 nm (near-infrared/deep red doublet). Because the flame is quite faint and easily overwhelmed by sodium's intense yellow, cobalt blue glass is used as a filter to block sodium emission and reveal potassium's true color.
安全上の警告
- Wear safety goggles at all times
- Keep hair tied back near open flames
- Handle HCl with care
必要なPPE
材料
-
Potassium chloride (KCl) (1 g)
-
Hydrochloric acid (HCl) (10 mL)1M concentration
-
Cobalt blue glass (1 piece)For filtering sodium light
器具
手順
Clean the nichrome wire thoroughly by dipping in HCl and heating.
Place potassium chloride on the watch glass and collect a sample on the clean wire.
Hold the sample in the Bunsen burner flame. Observe with the naked eye first.
Now observe the flame through cobalt blue glass to filter out any sodium contamination.
Record the difference in appearance with and without the cobalt blue glass filter.
予想される結果
Without the filter, you may see a faint lilac color possibly masked by yellow from sodium impurities. Through the cobalt blue glass, a clear violet/lilac flame should be visible as the glass absorbs the yellow sodium emission.
後片付け
Clean the wire loop with HCl. Return cobalt blue glass to storage.
詳細
- カテゴリ
- Flame Tests
- 難易度
- Beginner (Middle School)
- 所要時間
- 20 分
- 推定費用
- $6.00
- ステップ数
- 5
- 材料
- 3