Calcium Oxalate Precipitation (Kidney Stones)
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CaCl2 + Na2C2O4 → CaC2O4↓ + 2NaCl
概要
Calcium chloride reacts with sodium oxalate to form a white precipitate of calcium oxalate (Ksp = 2.3 × 10⁻⁹). Calcium oxalate is the primary component of approximately 80% of kidney stones. The monohydrate form (whewellite) is thermodynamically favored and forms the hardest, most painful stones.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Oxalic Acid C₂H₂O₄ | 1 | (aq) |
| 生成物 | Sodium Chloride NaCl | 2 | (aq) |
日常の例
Most kidney stones are calcium oxalate crystals. Foods high in oxalate (spinach, rhubarb, almonds) can increase stone risk.
産業上の重要性
シュウ酸カルシウム沈殿の理解は、腎臓学、食品科学(シュウ酸含有量分析)、そしてビール醸造(ビアストーン防止)において重要です。
特性
- タイプ
- Precipitation
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -12.0 kJ/mol