Hydrogen Peroxide Disproportionation
2H2O2 → 2H2O + O2
概要
Hydrogen peroxide simultaneously acts as both oxidizing and reducing agent in this disproportionation reaction. One molecule is reduced to water (O goes from -1 to -2) while another is oxidized to oxygen gas (O goes from -1 to 0). Manganese dioxide or the enzyme catalase dramatically accelerate this reaction.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Hydrogen Peroxide H₂O₂ | 2 | (aq) |
| 生成物 | Oxygen O | 1 | (g) |
| 生成物 | Water H₂O | 2 | (l) |
日常の例
The fizzing when hydrogen peroxide is applied to a wound occurs because catalase enzyme in blood rapidly decomposes H₂O₂, releasing oxygen bubbles.
産業上の重要性
H₂O₂の分解は廃水処理、高濃度H₂O₂ロケット推進剤、カタラーゼによる生体保護機構に利用される。MnO₂触媒分解は制御された酸素発生に使われる。
特性
- タイプ
- Redox
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -196.1 kJ/mol
- 触媒
- MnO₂ or catalase enzyme
関連する反応
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Iodine and Sodium Thiosulfate Titration
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Hydrogen Peroxide Disproportionation?
The balanced equation is: 2H₂O₂ → 2H₂O + O₂.
What type of reaction is Hydrogen Peroxide Disproportionation?
Hydrogen Peroxide Disproportionation is a redox reaction.
Is Hydrogen Peroxide Disproportionation exothermic or endothermic?
Hydrogen Peroxide Disproportionation is exothermic (releases energy). The enthalpy change (ΔH) is -196.1 kJ/mol.
What conditions are needed for Hydrogen Peroxide Disproportionation?
This reaction requires a catalyst (MnO₂ or catalase enzyme).