Hydrogen Peroxide Disproportionation
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2H2O2 → 2H2O + O2
概要
Hydrogen peroxide simultaneously acts as both oxidizing and reducing agent in this disproportionation reaction. One molecule is reduced to water (O goes from -1 to -2) while another is oxidized to oxygen gas (O goes from -1 to 0). Manganese dioxide or the enzyme catalase dramatically accelerate this reaction.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Hydrogen Peroxide H₂O₂ | 2 | (aq) |
| 生成物 | Oxygen O | 1 | (g) |
| 生成物 | Water H₂O | 2 | (l) |
日常の例
The fizzing when hydrogen peroxide is applied to a wound occurs because catalase enzyme in blood rapidly decomposes H₂O₂, releasing oxygen bubbles.
産業上の重要性
H₂O₂の分解は廃水処理、高濃度H₂O₂ロケット推進剤、カタラーゼによる生体保護機構に利用される。MnO₂触媒分解は制御された酸素発生に使われる。
特性
- タイプ
- Redox
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -196.1 kJ/mol
- 触媒
- MnO₂ or catalase enzyme