Methane Partial Oxidation (Steam Reforming)
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CH4 + H2O → CO + 3H2
概要
Methane reacts with steam over a nickel catalyst to produce synthesis gas (syngas), a mixture of carbon monoxide and hydrogen. Carbon is oxidized from -4 to +2 while hydrogen in water is reduced from +1 to 0. This highly endothermic reaction is performed at 700-1100 C and 15-30 atm.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Methane CH₄ | 1 | (g) |
| 反応物 | Water H₂O | 1 | (g) |
| 生成物 | Carbon Monoxide CO | 1 | (g) |
| 生成物 | Hydrogen H | 3 | (g) |
日常の例
Over 95% of the world's hydrogen is produced by this reaction, supplying hydrogen for ammonia production that feeds half the world's population.
産業上の重要性
スチームメタンリフォーミングは年間5,000万トン以上の水素を製造し、主にアンモニア合成と石油精製に利用される。グリーン水素電解法との競争が激しくなる中、コスト削減とCO₂回収が研究課題。
特性
- タイプ
- Redox
- 可逆的
- はい
- エネルギー
- 吸熱性
- ΔH
- 206.0 kJ/mol
- 触媒
- Nickel on alumina