Nickel Hydroxide Precipitation
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NiCl2 + 2NaOH → Ni(OH)2↓ + 2NaCl
概要
Nickel chloride reacts with sodium hydroxide to form a green precipitate of nickel(II) hydroxide (Ksp = 5.5 × 10⁻¹⁶). The apple-green precipitate does not dissolve in excess NaOH (not amphoteric) but dissolves in ammonia to form the deep blue hexaammine nickel(II) complex.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide NaOH | 2 | (aq) |
| 生成物 | Sodium Chloride NaCl | 2 | (aq) |
日常の例
Nickel hydroxide is the active material in rechargeable nickel-metal hydride (NiMH) batteries used in hybrid cars and consumer electronics.
産業上の重要性
水酸化ニッケルはNiCd・NiMH電池の正極活物質として、またニッケルめっき・触媒・新型電池正極材(ニッケルリッチLi-Ni-Mn-Co酸化物)の前駆体として重要な材料である。
特性
- タイプ
- Precipitation
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -55.0 kJ/mol