Oxidation of Ethanol to Acetaldehyde
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C2H5OH + [O] → CH3CHO + H2O
概要
Ethanol is oxidized to acetaldehyde, with the carbon bearing the OH group changing oxidation state from -1 to +1. In the body, this reaction is catalyzed by alcohol dehydrogenase in the liver. Acetaldehyde is toxic and is responsible for many hangover symptoms.
参加者
日常の例
When you drink alcohol, your liver enzymes perform this oxidation to break down ethanol. Acetaldehyde buildup causes hangover symptoms like headache and nausea.
産業上の重要性
エタノールからアセトアルデヒドへの工業的酸化(ワッカー法はエチレンにPdCl₂触媒を使用)は、酢酸やその他の化学物質の重要な中間体を生産する。
特性
- タイプ
- Redox
- 可逆的
- いいえ
- エネルギー
- 発熱性
- ΔH
- -175.0 kJ/mol
- 触媒
- Alcohol dehydrogenase (in liver)