マグネシウムを用いたガス化学量論
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Mgと塩酸の反応でモル体積を計算する
目的
既知の質量のマグネシウムリボンを過剰な塩酸と反応させ、室温条件下での水素ガスのモル体積を決定する。
背景
When magnesium reacts with HCl, hydrogen gas is produced: Mg + 2HCl → MgCl₂ + H₂. By measuring the mass of Mg used and the volume of H₂ collected, the molar volume at room conditions can be calculated and compared with the theoretical value at STP (22.4 L/mol).
安全上の警告
- HCl is corrosive
- Hydrogen is flammable — no flames
- Handle glassware carefully
必要なPPE
材料
-
Magnesium ribbon (0.1 g)Accurately weighed
-
Hydrochloric acid (HCl) (30 mL)2M, excess
-
Distilled water (500 mL)
器具
手順
Weigh a 3-4 cm strip of magnesium ribbon accurately. Record mass to 0.001 g.
Roll the Mg ribbon and secure it in a copper wire cage attached to a rubber stopper.
Fill the eudiometer tube with 2M HCl. Insert the stopper+Mg assembly, inverting the tube into the trough.
Allow the reaction to complete. All the Mg should dissolve, producing H₂ gas that collects at the top.
Equalize water levels inside and outside the tube. Read the gas volume at the meniscus.
Record room temperature and atmospheric pressure.
Correct for water vapor pressure. Calculate moles of H₂ from Mg mass. Determine molar volume.
予想される結果
0.1 g Mg = 0.00411 mol, producing 0.00411 mol H₂. At room conditions (~25°C, 1 atm), volume should be about 100 mL. Calculated molar volume at STP should be approximately 22.4 L/mol (±5%).
後片付け
Neutralize remaining HCl with NaHCO₃. Dispose down the drain. Rinse all equipment.
詳細
- カテゴリ
- Gas Laws
- 難易度
- Intermediate (High School)
- 所要時間
- 40 分
- 推定費用
- $8.00
- ステップ数
- 7
- 材料
- 3