Galvanic Corrosion of Zinc (Sacrificial Anode)
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Zn → Zn2+ + 2e−
概要
Zinc acts as a sacrificial anode when electrically connected to iron or steel, preferentially oxidizing to protect the less reactive metal. Zinc's standard reduction potential (-0.76 V) is more negative than iron's (-0.44 V), so zinc corrodes first. This is the principle of cathodic protection and galvanization.
参加者
| 役割 | 物質 | 係数 | 状態 |
|---|---|---|---|
| 反応物 | Zinc Zn | 1 | (s) |
日常の例
Galvanized steel roofing, fencing, and car bodies are coated with zinc that corrodes preferentially, protecting the steel underneath.
産業上の重要性
亜鉛めっきは年間1億トン以上の鉄鋼を保護する。犠牲亜鉛陽極は船舶、海洋構造物、地中埋設パイプラインの電気防食に使われ、腐食コストを大幅に削減する。
特性
- タイプ
- Redox
- 可逆的
- いいえ
- エネルギー
- 発熱性