Vanadium Redox Flow Battery
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V2+ + VO2+ + 2H+ ⇌ V3+ + VO2+ + H2O
概要
The vanadium redox flow battery (VRFB) uses four oxidation states of vanadium (V²⁺/V³⁺ and VO²⁺/VO₂⁺) in two electrolyte tanks. During discharge, V²⁺ is oxidized to V³⁺ at the negative electrode while VO₂⁺ is reduced to VO²⁺ at the positive electrode. Using the same element eliminates cross-contamination.
参加者
日常の例
Large VRFB installations store renewable energy from wind and solar farms, releasing it when the sun is not shining or wind is not blowing.
産業上の重要性
バナジウムフロー電池は数百MWhの容量を持つ系統規模のエネルギー貯蔵に使用される。20年以上の寿命と無制限の充放電サイクルを提供する。
特性
- タイプ
- Redox
- 可逆的
- はい
- エネルギー
- 発熱性
- ΔH
- -121.0 kJ/mol