Vanadium Redox Flow Battery
V2+ + VO2+ + 2H+ ⇌ V3+ + VO2+ + H2O
概要
The vanadium redox flow battery (VRFB) uses four oxidation states of vanadium (V²⁺/V³⁺ and VO²⁺/VO₂⁺) in two electrolyte tanks. During discharge, V²⁺ is oxidized to V³⁺ at the negative electrode while VO₂⁺ is reduced to VO²⁺ at the positive electrode. Using the same element eliminates cross-contamination.
参加者
日常の例
Large VRFB installations store renewable energy from wind and solar farms, releasing it when the sun is not shining or wind is not blowing.
産業上の重要性
バナジウムフロー電池は数百MWhの容量を持つ系統規模のエネルギー貯蔵に使用される。20年以上の寿命と無制限の充放電サイクルを提供する。
特性
- タイプ
- Redox
- 可逆的
- はい
- エネルギー
- 発熱性
- ΔH
- -121.0 kJ/mol
関連する反応
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Vanadium Redox Flow Battery?
The balanced equation is: V²⁺ + VO₂⁺ + 2H⁺ ⇌ V³⁺ + VO²⁺ + H₂O.
What type of reaction is Vanadium Redox Flow Battery?
Vanadium Redox Flow Battery is a redox reaction. It is reversible under certain conditions.
Is Vanadium Redox Flow Battery exothermic or endothermic?
Vanadium Redox Flow Battery is exothermic (releases energy). The enthalpy change (ΔH) is -121.0 kJ/mol.