钾焰色反应
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通过紫丁香/紫色火焰鉴定钾
目标
观察钾离子产生的紫丁香/紫色火焰,学习使用钴蓝玻璃区分钾与钠污染。
背景
Potassium produces a pale lilac or violet flame when heated. The emission occurs at 766.5 nm and 769.9 nm (near-infrared/deep red doublet). Because the flame is quite faint and easily overwhelmed by sodium's intense yellow, cobalt blue glass is used as a filter to block sodium emission and reveal potassium's true color.
安全警告
- Wear safety goggles at all times
- Keep hair tied back near open flames
- Handle HCl with care
所需PPE
材料
-
Potassium chloride (KCl) (1 g)
-
Hydrochloric acid (HCl) (10 mL)1M concentration
-
Cobalt blue glass (1 piece)For filtering sodium light
设备
步骤
Clean the nichrome wire thoroughly by dipping in HCl and heating.
Place potassium chloride on the watch glass and collect a sample on the clean wire.
Hold the sample in the Bunsen burner flame. Observe with the naked eye first.
Now observe the flame through cobalt blue glass to filter out any sodium contamination.
Record the difference in appearance with and without the cobalt blue glass filter.
预期结果
Without the filter, you may see a faint lilac color possibly masked by yellow from sodium impurities. Through the cobalt blue glass, a clear violet/lilac flame should be visible as the glass absorbs the yellow sodium emission.
清理
Clean the wire loop with HCl. Return cobalt blue glass to storage.
详情
- 类别
- Flame Tests
- 难度
- Beginner (Middle School)
- 时长
- 20 分钟
- 预估费用
- $6.00
- 步骤数
- 5
- 材料
- 3