Electrorefining of Copper
Cu (impure) → Cu2+ + 2e− → Cu (pure)
概述
Impure copper anodes (99.5%) dissolve electrochemically while pure copper (99.99%) deposits at the cathode from CuSO₄/H₂SO₄ electrolyte. Impurities either remain in solution or fall as anode slime (containing gold, silver, platinum). The voltage required is only 0.2–0.3 V since the same reaction occurs at both electrodes.
参与者
日常示例
All the copper wiring in your home was refined to 99.99% purity by this electrorefining process.
工业重要性
电解精炼是生产电子级高纯铜的标准方法,全球年电解铜产量超2000万吨。精炼过程中阳极泥还富集金、银、铂族金属等贵金属副产品。
属性
- 可逆
- 否
- 能量
- 吸热
- ΔH
- 0.0 kJ/mol
相关反应
Alkaline Battery Discharge
Anodizing of Aluminum
Chlor-Alkali Electrolysis
Nickel-Metal Hydride Battery
Daniell Cell (Zinc-Copper Galvanic Cell)
Electrolysis of Molten NaCl (Downs Process)
Lead-Acid Battery Discharge
Hall-Héroult Process (Aluminum Smelting)
Electrowinning of Zinc
Electrolysis of Water
Frequently Asked Questions
What is the equation for Electrorefining of Copper?
The balanced equation is: Cu (impure) → Cu²⁺ + 2e⁻ → Cu (pure).
What type of reaction is Electrorefining of Copper?
Electrorefining of Copper is a electrochemical reaction.
Is Electrorefining of Copper exothermic or endothermic?
Electrorefining of Copper is endothermic (absorbs energy). The enthalpy change (ΔH) is 0.0 kJ/mol.