Iron(II) Sulfide Precipitation
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FeSO4 + Na2S → FeS↓ + Na2SO4
概述
Iron(II) sulfate reacts with sodium sulfide to form a black precipitate of iron(II) sulfide (Ksp = 6 × 10⁻¹⁸). FeS reacts with dilute acids to produce hydrogen sulfide gas with its characteristic rotten egg smell. The mineral form is troilite, found in meteorites.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 产物 | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
日常示例
The black spots in hard-boiled eggs at the yolk-white junction are iron sulfide, formed by reaction of iron in the yolk with sulfur from the egg white.
工业重要性
硫化亚铁在石油工业中作为酸性气体(H₂S)与铁设备的腐蚀产物大量出现,是套管、管道腐蚀失效的重要原因,也是陨磁铁矿(磁黄铁矿)的主要矿物。
属性
- 可逆
- 否
- 能量
- 放热
- ΔH
- -75.0 kJ/mol