Lead Carbonate Precipitation
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Pb(NO3)2 + Na2CO3 → PbCO3↓ + 2NaNO3
概述
Lead nitrate reacts with sodium carbonate to form a white precipitate of lead carbonate (Ksp = 7.4 × 10⁻¹⁴). Basic lead carbonate (2PbCO₃·Pb(OH)₂), known as white lead, was the most important white pigment for millennia until its toxicity led to replacement by titanium dioxide.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 反应物 | Sodium Carbonate Na₂CO₃ | 1 | (aq) |
| 产物 | Sodium Nitrate NaNO₃ | 2 | (aq) |
日常示例
White lead paint was used in homes for centuries before being banned due to lead poisoning, especially dangerous for children.
工业重要性
碳酸铅(铅白)因毒性已被TiO₂全面取代,但了解铅的沉淀化学对铅污染土壤和水体的修复治理(如磷酸固化铅)仍具重要工程意义。
属性
- 可逆
- 否
- 能量
- 放热
- ΔH
- -22.0 kJ/mol