Iron(III) Hydroxide Precipitation
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FeCl3 + 3NaOH → Fe(OH)3↓ + 3NaCl
概述
Iron(III) chloride reacts with sodium hydroxide to form a rust-brown gelatinous precipitate of iron(III) hydroxide. Fe(OH)₃ has an extremely low Ksp of 2.8 × 10⁻³⁹, precipitating even at slightly acidic pH. The gelatinous nature makes it an excellent flocculant for water treatment.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 反应物 | Iron(III) Chloride FeCl₃ | 1 | (aq) |
| 反应物 | Sodium Hydroxide NaOH | 3 | (aq) |
| 产物 | Sodium Chloride NaCl | 3 | (aq) |
日常示例
The rust-colored sludge in water treatment plants is mainly iron(III) hydroxide precipitated by adding base to iron-rich water.
工业重要性
氢氧化铁沉淀是饮用水除铁的首选方法,也是污水处理中重要的絮凝剂,用于去除磷酸盐、重金属和悬浮固体,全球水处理行业每年消耗大量铁盐絮凝剂。
属性
- 可逆
- 否
- 能量
- 放热
- ΔH
- -88.0 kJ/mol