التبلور الطارد للحرارة لأسيتات الصوديوم
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قياس الحرارة المنبعثة أثناء التبلور الفوري
الهدف
قياس الحرارة المنبعثة أثناء تبلور أسيتات الصوديوم مشبعة الفائق باستخدام القياس الحراري.
الخلفية
When supersaturated sodium acetate crystallizes, it releases stored energy as heat. By triggering crystallization inside a calorimeter and measuring the temperature rise, the enthalpy of crystallization can be determined. This is the same principle used in reusable hand warmers.
تحذيرات السلامة
- Hot solution during preparation
- Crystallization releases heat — container gets warm
معدات الوقاية الشخصية المطلوبة
المواد
-
Sodium acetate trihydrate (80 g)
-
Distilled water (150 mL)
المعدات
الإجراء
Dissolve 80 g sodium acetate trihydrate in 20 mL water by heating to about 70°C. Stir until clear.
Pour the solution into the polystyrene cup calorimeter. Allow to cool undisturbed to room temperature.
Record the temperature of the supersaturated solution.
Add a single small crystal of sodium acetate to trigger crystallization. Immediately stir gently and record temperature every 15 seconds.
Record the maximum temperature reached.
Calculate the heat released: q = mcΔT. Determine ΔH of crystallization per mole.
النتائج المتوقعة
Temperature should rise 15-25°C above room temperature. The enthalpy of crystallization is approximately -19.7 kJ/mol for sodium acetate trihydrate. Measured values should be within 20% of this.
التنظيف
The sodium acetate can be remelted and reused. Rinse the calorimeter. Non-toxic — can go down the drain.
التفاصيل
- الفئة
- Thermochemistry
- الصعوبة
- Intermediate (High School)
- المدة
- 30 دقيقة
- التكلفة التقديرية
- $8,00
- الخطوات
- 6
- المواد
- 2