Galvanic Corrosion of Zinc (Sacrificial Anode)
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Zn → Zn2+ + 2e−
概述
Zinc acts as a sacrificial anode when electrically connected to iron or steel, preferentially oxidizing to protect the less reactive metal. Zinc's standard reduction potential (-0.76 V) is more negative than iron's (-0.44 V), so zinc corrodes first. This is the principle of cathodic protection and galvanization.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 反应物 | Zinc Zn | 1 | (s) |
日常示例
Galvanized steel roofing, fencing, and car bodies are coated with zinc that corrodes preferentially, protecting the steel underneath.
工业重要性
牺牲阳极保护法广泛用于保护船舶、海洋石油平台、地下管道和储罐中的钢铁设施。镀锌钢(热浸镀锌或电镀锌)利用同样原理保护钢铁,全球每年消耗约600万吨锌用于镀锌保护,显著延长金属设施寿命。
属性
- 类型
- Redox
- 可逆
- 否
- 能量
- 放热