Lead Chloride Precipitation
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Pb(NO3)2 + 2NaCl → PbCl2↓ + 2NaNO3
概述
Lead nitrate reacts with sodium chloride to form a white precipitate of lead chloride (Ksp = 1.7 × 10⁻⁵). PbCl₂ is moderately insoluble at room temperature but becomes quite soluble in hot water, distinguishing it from AgCl. The precipitate consists of fine needle-like crystals.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 反应物 | Sodium Chloride NaCl | 2 | (aq) |
| 产物 | Sodium Nitrate NaNO₃ | 2 | (aq) |
日常示例
In qualitative analysis, PbCl₂ is separated from AgCl and Hg₂Cl₂ by dissolving it in hot water, a key step in Group I cation analysis.
工业重要性
氯化铅沉淀是铅回收工艺(火法精炼富集)和铅离子的定性分析(与AgCl和Hg₂Cl₂同属难溶氯化物)的化学基础,也用于了解铅在水处理中的行为。
属性
- 可逆
- 否
- 能量
- 放热
- ΔH
- -14.0 kJ/mol