Nickel Hydroxide Precipitation
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NiCl2 + 2NaOH → Ni(OH)2↓ + 2NaCl
概述
Nickel chloride reacts with sodium hydroxide to form a green precipitate of nickel(II) hydroxide (Ksp = 5.5 × 10⁻¹⁶). The apple-green precipitate does not dissolve in excess NaOH (not amphoteric) but dissolves in ammonia to form the deep blue hexaammine nickel(II) complex.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 反应物 | Sodium Hydroxide NaOH | 2 | (aq) |
| 产物 | Sodium Chloride NaCl | 2 | (aq) |
日常示例
Nickel hydroxide is the active material in rechargeable nickel-metal hydride (NiMH) batteries used in hybrid cars and consumer electronics.
工业重要性
氢氧化镍是NiCd和NiMH电池的正极活性材料,也是镍镀层的重要中间体和催化剂前体。丰田普锐斯等混合动力汽车大量采用NiMH电池。
属性
- 可逆
- 否
- 能量
- 放热
- ΔH
- -55.0 kJ/mol