Ostwald Process NO Oxidation

4NH3 + 5O2 → 4NO + 6H2O

概述

Ammonia is catalytically oxidized to nitric oxide over a platinum-rhodium gauze catalyst at about 850 C in the Ostwald process. Nitrogen is oxidized from -3 in NH₃ to +2 in NO. The NO is further oxidized to NO₂ and absorbed in water to make nitric acid. This process links the Haber process to nitric acid production.

参与者

角色 物质 系数 状态
反应物 Ammonia NH₃ 4 (g)
反应物 Oxygen O 5 (g)
产物 Water H₂O 6 (g)

日常示例

Nearly all explosives, from TNT to ammonium nitrate, begin with nitric acid produced by this catalytic oxidation of ammonia.

工业重要性

全球每年通过该工艺生产约8000万吨硝酸,主要用于化肥(硝酸铵)和炸药(硝化甘油、TNT)的制造。

Frequently Asked Questions

What is the equation for Ostwald Process NO Oxidation?
The balanced equation is: 4NH₃ + 5O₂ → 4NO + 6H₂O.
What type of reaction is Ostwald Process NO Oxidation?
Ostwald Process NO Oxidation is a redox reaction.
Is Ostwald Process NO Oxidation exothermic or endothermic?
Ostwald Process NO Oxidation is exothermic (releases energy). The enthalpy change (ΔH) is -905.0 kJ/mol.
What conditions are needed for Ostwald Process NO Oxidation?
This reaction requires a catalyst (Platinum-rhodium gauze).