Ostwald Process NO Oxidation
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4NH3 + 5O2 → 4NO + 6H2O
概述
Ammonia is catalytically oxidized to nitric oxide over a platinum-rhodium gauze catalyst at about 850 C in the Ostwald process. Nitrogen is oxidized from -3 in NH₃ to +2 in NO. The NO is further oxidized to NO₂ and absorbed in water to make nitric acid. This process links the Haber process to nitric acid production.
参与者
日常示例
Nearly all explosives, from TNT to ammonium nitrate, begin with nitric acid produced by this catalytic oxidation of ammonia.
工业重要性
全球每年通过该工艺生产约8000万吨硝酸,主要用于化肥(硝酸铵)和炸药(硝化甘油、TNT)的制造。
属性
- 类型
- Redox
- 可逆
- 否
- 能量
- 放热
- ΔH
- -905.0 kJ/mol
- 催化剂
- Platinum-rhodium gauze