Tollen's Test (Silver Mirror)

RCHO + 2Ag(NH3)2+ + 2OH → RCOO + 2Ag + 4NH3 + H2O

概述

Tollens' reagent (silver-ammonia complex) is reduced to metallic silver by aldehydes, producing a silver mirror on the test tube walls. The aldehyde is oxidized to a carboxylate. This test distinguishes aldehydes from ketones, as ketones cannot be easily oxidized. It was historically used for mirror manufacturing.

参与者

角色 物质 系数 状态
产物 Water H₂O 1 (l)
产物 Silver Ag 2 (s)
产物 Ammonia NH₃ 4 (aq)

日常示例

The silver mirror test creates a beautiful reflective coating on glass, and this chemistry was actually used to make mirrors commercially.

工业重要性

银镜反应用于有机化学中醛类的定性鉴定,也是传统镜面镀银工艺的化学基础,工艺优雅且有历史意义。

Frequently Asked Questions

What is the equation for Tollen's Test (Silver Mirror)?
The balanced equation is: RCHO + 2Ag(NH₃)₂⁺ + 2OH⁻ → RCOO⁻ + 2Ag + 4NH₃ + H₂O.
What type of reaction is Tollen's Test (Silver Mirror)?
Tollen's Test (Silver Mirror) is a redox reaction.
Is Tollen's Test (Silver Mirror) exothermic or endothermic?
Tollen's Test (Silver Mirror) is exothermic (releases energy). The enthalpy change (ΔH) is -135.0 kJ/mol.