Tollen's Test (Silver Mirror)
RCHO + 2Ag(NH3)2+ + 2OH− → RCOO− + 2Ag + 4NH3 + H2O
概述
Tollens' reagent (silver-ammonia complex) is reduced to metallic silver by aldehydes, producing a silver mirror on the test tube walls. The aldehyde is oxidized to a carboxylate. This test distinguishes aldehydes from ketones, as ketones cannot be easily oxidized. It was historically used for mirror manufacturing.
参与者
日常示例
The silver mirror test creates a beautiful reflective coating on glass, and this chemistry was actually used to make mirrors commercially.
工业重要性
银镜反应用于有机化学中醛类的定性鉴定,也是传统镜面镀银工艺的化学基础,工艺优雅且有历史意义。
属性
- 类型
- Redox
- 可逆
- 否
- 能量
- 放热
- ΔH
- -135.0 kJ/mol
相关反应
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Tollen's Test (Silver Mirror)?
The balanced equation is: RCHO + 2Ag(NH₃)₂⁺ + 2OH⁻ → RCOO⁻ + 2Ag + 4NH₃ + H₂O.
What type of reaction is Tollen's Test (Silver Mirror)?
Tollen's Test (Silver Mirror) is a redox reaction.
Is Tollen's Test (Silver Mirror) exothermic or endothermic?
Tollen's Test (Silver Mirror) is exothermic (releases energy). The enthalpy change (ΔH) is -135.0 kJ/mol.