Tollen's Test (Silver Mirror)
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RCHO + 2Ag(NH3)2+ + 2OH− → RCOO− + 2Ag + 4NH3 + H2O
概述
Tollens' reagent (silver-ammonia complex) is reduced to metallic silver by aldehydes, producing a silver mirror on the test tube walls. The aldehyde is oxidized to a carboxylate. This test distinguishes aldehydes from ketones, as ketones cannot be easily oxidized. It was historically used for mirror manufacturing.
参与者
日常示例
The silver mirror test creates a beautiful reflective coating on glass, and this chemistry was actually used to make mirrors commercially.
工业重要性
银镜反应用于有机化学中醛类的定性鉴定,也是传统镜面镀银工艺的化学基础,工艺优雅且有历史意义。
属性
- 类型
- Redox
- 可逆
- 否
- 能量
- 放热
- ΔH
- -135.0 kJ/mol