Vanadium Redox Flow Battery
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V2+ + VO2+ + 2H+ ⇌ V3+ + VO2+ + H2O
概述
The vanadium redox flow battery (VRFB) uses four oxidation states of vanadium (V²⁺/V³⁺ and VO²⁺/VO₂⁺) in two electrolyte tanks. During discharge, V²⁺ is oxidized to V³⁺ at the negative electrode while VO₂⁺ is reduced to VO²⁺ at the positive electrode. Using the same element eliminates cross-contamination.
参与者
日常示例
Large VRFB installations store renewable energy from wind and solar farms, releasing it when the sun is not shining or wind is not blowing.
工业重要性
钒液流电池用于电网级储能,容量可达数百兆瓦时,使用寿命超过20年,可无限次循环充放电,是清洁能源存储的重要技术。
属性
- 类型
- Redox
- 可逆
- 是
- 能量
- 放热
- ΔH
- -121.0 kJ/mol