Vanadium Redox Flow Battery

V2+ + VO2+ + 2H+ ⇌ V3+ + VO2+ + H2O

概述

The vanadium redox flow battery (VRFB) uses four oxidation states of vanadium (V²⁺/V³⁺ and VO²⁺/VO₂⁺) in two electrolyte tanks. During discharge, V²⁺ is oxidized to V³⁺ at the negative electrode while VO₂⁺ is reduced to VO²⁺ at the positive electrode. Using the same element eliminates cross-contamination.

参与者

角色 物质 系数 状态
反应物 Vanadium V 1 (aq)
产物 Water H₂O 1 (l)

日常示例

Large VRFB installations store renewable energy from wind and solar farms, releasing it when the sun is not shining or wind is not blowing.

工业重要性

钒液流电池用于电网级储能,容量可达数百兆瓦时,使用寿命超过20年,可无限次循环充放电,是清洁能源存储的重要技术。

Frequently Asked Questions

What is the equation for Vanadium Redox Flow Battery?
The balanced equation is: V²⁺ + VO₂⁺ + 2H⁺ ⇌ V³⁺ + VO²⁺ + H₂O.
What type of reaction is Vanadium Redox Flow Battery?
Vanadium Redox Flow Battery is a redox reaction. It is reversible under certain conditions.
Is Vanadium Redox Flow Battery exothermic or endothermic?
Vanadium Redox Flow Battery is exothermic (releases energy). The enthalpy change (ΔH) is -121.0 kJ/mol.