活動列の確認
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置換反応で金属の反応性を試験する
目的
金属が溶液中の他の金属を置換できるかどうかを試験し、電気化学的活動列を確認する。
背景
A more reactive (more easily oxidized) metal will displace a less reactive metal from its salt solution. By testing multiple combinations, students can experimentally construct the activity series: Zn > Fe > Cu > Ag.
安全上の警告
- Silver nitrate stains skin permanently
- Copper sulfate is toxic
- Wear gloves when handling solutions
必要なPPE
材料
-
Zinc strips (3 pieces)Small pieces
-
Iron nails (3)Clean steel nails
-
Copper strips (3 pieces)
-
Copper(II) sulfate solution (50 mL)0.1M
-
Iron(II) sulfate solution (50 mL)0.1M
-
Zinc sulfate solution (50 mL)0.1M
-
Silver nitrate solution (30 mL)0.1M
器具
手順
Sand all metal pieces until shiny to remove oxide layers.
Place 10 mL of each metal salt solution into labeled test tubes. You need: CuSO₄, FeSO₄, ZnSO₄, and AgNO₃.
Test zinc in CuSO₄ solution. Observe for 5 minutes and record changes on the metal and in the solution.
Test iron in CuSO₄ solution. Observe and record.
Test copper in ZnSO₄ solution. Observe and record (expect no reaction).
Test copper in AgNO₃ solution. Observe silver crystals forming on the copper.
Compile results into a reactivity table and rank the metals from most to least reactive.
予想される結果
Zinc displaces copper (blue solution fades, copper deposits on zinc). Iron displaces copper (blue fades slower). Copper does not displace zinc. Copper displaces silver (silver crystals grow). Order: Zn > Fe > Cu > Ag.
後片付け
Collect silver waste separately in heavy metal container. Dispose of copper waste properly. Rinse metal pieces and test tubes.
詳細
- カテゴリ
- Electrochemistry
- 難易度
- Beginner (Middle School)
- 所要時間
- 30 分
- 推定費用
- $12.00
- ステップ数
- 7
- 材料
- 7