镁的气体化学计量学
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通过Mg与HCl反应计算摩尔体积
目标
通过已知质量的镁条与过量盐酸反应,测定室温条件下氢气的摩尔体积。
背景
When magnesium reacts with HCl, hydrogen gas is produced: Mg + 2HCl → MgCl₂ + H₂. By measuring the mass of Mg used and the volume of H₂ collected, the molar volume at room conditions can be calculated and compared with the theoretical value at STP (22.4 L/mol).
安全警告
- HCl is corrosive
- Hydrogen is flammable — no flames
- Handle glassware carefully
所需PPE
材料
-
Magnesium ribbon (0.1 g)Accurately weighed
-
Hydrochloric acid (HCl) (30 mL)2M, excess
-
Distilled water (500 mL)
设备
步骤
Weigh a 3-4 cm strip of magnesium ribbon accurately. Record mass to 0.001 g.
Roll the Mg ribbon and secure it in a copper wire cage attached to a rubber stopper.
Fill the eudiometer tube with 2M HCl. Insert the stopper+Mg assembly, inverting the tube into the trough.
Allow the reaction to complete. All the Mg should dissolve, producing H₂ gas that collects at the top.
Equalize water levels inside and outside the tube. Read the gas volume at the meniscus.
Record room temperature and atmospheric pressure.
Correct for water vapor pressure. Calculate moles of H₂ from Mg mass. Determine molar volume.
预期结果
0.1 g Mg = 0.00411 mol, producing 0.00411 mol H₂. At room conditions (~25°C, 1 atm), volume should be about 100 mL. Calculated molar volume at STP should be approximately 22.4 L/mol (±5%).
清理
Neutralize remaining HCl with NaHCO₃. Dispose down the drain. Rinse all equipment.
详情
- 类别
- Gas Laws
- 难度
- Intermediate (High School)
- 时长
- 40 分钟
- 预估费用
- $8.00
- 步骤数
- 7
- 材料
- 3