Fenton's Reaction
Fe2+ + H2O2 → Fe3+ + OH− + OH·
概述
Fenton's reagent generates highly reactive hydroxyl radicals (OH·) from iron(II) and hydrogen peroxide. The hydroxyl radical is one of the strongest oxidizers known, capable of degrading virtually any organic compound. Fe²⁺ is oxidized to Fe³⁺ while H₂O₂ is reduced.
参与者
| 角色 | 物质 | 系数 | 状态 |
|---|---|---|---|
| 反应物 | Hydrogen Peroxide H₂O₂ | 1 | (aq) |
日常示例
Fenton's chemistry occurs naturally in the body when iron and hydrogen peroxide interact, which is why excess free iron can cause oxidative damage.
工业重要性
芬顿反应被广泛用于工业废水处理,尤其是难以生物降解的有机污染物(如农药、染料、药物残留)的深度处理,全球已有数千套工业装置投入运行。
属性
- 类型
- Redox
- 可逆
- 否
- 能量
- 放热
- ΔH
- -40.0 kJ/mol
相关反应
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Fenton's Reaction?
The balanced equation is: Fe²⁺ + H₂O₂ → Fe³⁺ + OH⁻ + OH·.
What type of reaction is Fenton's Reaction?
Fenton's Reaction is a redox reaction.
Is Fenton's Reaction exothermic or endothermic?
Fenton's Reaction is exothermic (releases energy). The enthalpy change (ΔH) is -40.0 kJ/mol.