Polymerization of Vinyl Chloride to PVC

nCH2=CHCl → (–CH2–CHCl–)n

概述

Vinyl chloride monomer (VCM) undergoes free radical addition polymerization to form polyvinyl chloride (PVC), the third most produced plastic worldwide. PVC is rigid by default but can be made flexible with plasticizers. Suspension polymerization is the most common industrial method.

日常示例

PVC pipes, vinyl flooring, window frames, wire insulation, and credit cards are all made from this polymerization reaction.

工业重要性

PVC每年产量超过4500万吨，广泛用于建筑管材、电线绝缘层、地板和医疗器械，是不可或缺的工业材料。

属性

类型
Organic
可逆
否
能量
放热
ΔH
-72.0 kJ/mol
催化剂
Free radical initiators

相关反应

Epoxidation of Alkenes (mCPBA) Swern Oxidation Oxidation of Secondary Alcohol to Ketone E2 Elimination (Dehydrohalogenation) Claisen Condensation (Ethyl Acetate) Aldol Condensation of Acetaldehyde Kolbe Electrolysis Baeyer-Villiger Oxidation Beckmann Rearrangement (Cyclohexanone Oxime) Dehydration of Ethanol

Frequently Asked Questions

What is the equation for Polymerization of Vinyl Chloride to PVC?
The balanced equation is: nCH₂=CHCl → (–CH₂–CHCl–)ₙ.
What type of reaction is Polymerization of Vinyl Chloride to PVC?
Polymerization of Vinyl Chloride to PVC is a organic reaction.
Is Polymerization of Vinyl Chloride to PVC exothermic or endothermic?
Polymerization of Vinyl Chloride to PVC is exothermic (releases energy). The enthalpy change (ΔH) is -72.0 kJ/mol.
What conditions are needed for Polymerization of Vinyl Chloride to PVC?
This reaction requires a catalyst (Free radical initiators).