Calcium Sulfate Precipitation (Gypsum)
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Ca(NO3)2 + Na2SO4 → CaSO4↓ + 2NaNO3
Tổng quan
Calcium nitrate reacts with sodium sulfate to precipitate calcium sulfate (Ksp = 4.9 × 10⁻⁵). CaSO₄ is sparingly soluble, not truly insoluble. The dihydrate form (CaSO₄·2H₂O) is gypsum, one of the most important construction materials. Plaster of Paris is the hemihydrate form.
Người tham gia
| Vai trò | Chất | Hệ số | Trạng thái |
|---|---|---|---|
| Chất phản ứng | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
| Sản phẩm | Calcium Sulfate CaSO₄ | 1 | (s) |
| Sản phẩm | Sodium Nitrate NaNO₃ | 2 | (aq) |
Ví dụ thực tế
Drywall (gypsum board) used in nearly every building contains calcium sulfate dihydrate, produced by similar precipitation chemistry.
Tầm quan trọng công nghiệp
Gypsum production exceeds 250 million tonnes annually for drywall, plaster, cement, and soil amendment. FGD gypsum from power plants is increasingly important.
Tính chất
- Loại
- Precipitation
- Thuận nghịch
- Không
- Năng lượng
- Tỏa nhiệt
- ΔH
- -8,0 kJ/mol