Copper Sulfide Precipitation
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CuSO4 + Na2S → CuS↓ + Na2SO4
Tổng quan
Copper sulfate reacts with sodium sulfide to form a black precipitate of copper(II) sulfide (Ksp = 1.3 × 10⁻³⁶). CuS is one of the most insoluble compounds known. The jet-black precipitate forms instantly and is used to identify Cu²⁺ ions in systematic qualitative analysis.
Người tham gia
| Vai trò | Chất | Hệ số | Trạng thái |
|---|---|---|---|
| Chất phản ứng | Copper(II) Sulfate CuSO₄ | 1 | (aq) |
| Sản phẩm | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
Ví dụ thực tế
The black tarnish on copper pots exposed to sulfur-containing foods (eggs, garlic) is related to copper sulfide formation.
Tầm quan trọng công nghiệp
Sulfide precipitation is used in mining wastewater treatment to remove heavy metals. CuS (covellite) is also a naturally occurring copper ore mineral.
Tính chất
- Loại
- Precipitation
- Thuận nghịch
- Không
- Năng lượng
- Tỏa nhiệt
- ΔH
- -84,0 kJ/mol