Iron(II) to Iron(III) Oxidation by Oxygen
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4Fe2+ + O2 + 4H+ → 4Fe3+ + 2H2O
Tổng quan
Ferrous ions (Fe²⁺) are oxidized to ferric ions (Fe³⁺) by dissolved oxygen in acidic solution. This reaction is responsible for the yellowing of iron-containing groundwater upon exposure to air. The green Fe²⁺ solution turns yellow-brown as Fe³⁺ forms.
Người tham gia
Ví dụ thực tế
Well water that is clear underground but turns rusty brown when left standing is undergoing this oxidation of dissolved iron(II) by air.
Tầm quan trọng công nghiệp
Iron(II)/iron(III) redox chemistry is fundamental to water treatment, geochemistry, soil science, and corrosion engineering.
Tính chất
- Loại
- Redox
- Thuận nghịch
- Không
- Năng lượng
- Tỏa nhiệt
- ΔH
- -176,0 kJ/mol