Calcium Oxalate Precipitation (Kidney Stones)
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CaCl2 + Na2C2O4 → CaC2O4↓ + 2NaCl
Tổng quan
Calcium chloride reacts with sodium oxalate to form a white precipitate of calcium oxalate (Ksp = 2.3 × 10⁻⁹). Calcium oxalate is the primary component of approximately 80% of kidney stones. The monohydrate form (whewellite) is thermodynamically favored and forms the hardest, most painful stones.
Người tham gia
| Vai trò | Chất | Hệ số | Trạng thái |
|---|---|---|---|
| Chất phản ứng | Oxalic Acid C₂H₂O₄ | 1 | (aq) |
| Sản phẩm | Sodium Chloride NaCl | 2 | (aq) |
Ví dụ thực tế
Most kidney stones are calcium oxalate crystals. Foods high in oxalate (spinach, rhubarb, almonds) can increase stone risk.
Tầm quan trọng công nghiệp
Understanding calcium oxalate precipitation is critical in nephrology, food science (oxalate content analysis), and in beer brewing (beer stone prevention).
Tính chất
- Loại
- Precipitation
- Thuận nghịch
- Không
- Năng lượng
- Tỏa nhiệt
- ΔH
- -12,0 kJ/mol