Sulfur Dioxide Reduction of Dichromate
Cr2O72− + 3SO2 + 2H+ → 2Cr3+ + 3SO42− + H2O
Tổng quan
Sulfur dioxide reduces orange dichromate to green chromium(III) while being oxidized to sulfate. This reaction changes the solution color from orange to green and is used as a test for SO₂ gas. Cr(VI) gains 3 electrons per atom while S(IV) loses 2 electrons per atom.
Người tham gia
| Vai trò | Chất | Hệ số | Trạng thái |
|---|---|---|---|
| Chất phản ứng | Sulfur Dioxide SO₂ | 3 | (g) |
| Sản phẩm | Water H₂O | 1 | (l) |
Ví dụ thực tế
Dichromate-impregnated paper is used as a sensitive test for sulfur dioxide gas, turning from orange to green in its presence.
Tầm quan trọng công nghiệp
This reaction is relevant to flue gas monitoring, environmental SO₂ detection, and understanding chromium redox chemistry in industrial processes.
Tính chất
- Loại
- Redox
- Thuận nghịch
- Không
- Năng lượng
- Tỏa nhiệt
- ΔH
- -850,0 kJ/mol
Phản ứng liên quan
Iron(II) to Iron(III) Oxidation by Oxygen
Bleaching with Sodium Hypochlorite
Copper Reduction of Silver Ion
Aqua Regia Dissolving Gold
Cerium(IV) Reduction by Iron(II)
Copper Oxidation by Nitric Acid
Hypochlorite Oxidation of Hydrogen Peroxide
Hydrogen Peroxide as Oxidizing Agent (Acidic)
Hydrogen Peroxide Disproportionation
Displacement of Hydrogen from Acid by Magnesium
Frequently Asked Questions
What is the equation for Sulfur Dioxide Reduction of Dichromate?
The balanced equation is: Cr₂O₇²⁻ + 3SO₂ + 2H⁺ → 2Cr³⁺ + 3SO₄²⁻ + H₂O.
What type of reaction is Sulfur Dioxide Reduction of Dichromate?
Sulfur Dioxide Reduction of Dichromate is a redox reaction.
Is Sulfur Dioxide Reduction of Dichromate exothermic or endothermic?
Sulfur Dioxide Reduction of Dichromate is exothermic (releases energy). The enthalpy change (ΔH) is -850.0 kJ/mol.