Phản Ứng Natri với Nước
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Quan sát phản ứng mãnh liệt của kim loại kiềm với nước
Mục tiêu
Minh họa tính hoạt động của kim loại kiềm bằng cách cho natri phản ứng với nước, quan sát sự sinh khí hydro và tạo thành hydroxit.
Bối cảnh
Sodium metal reacts vigorously with water in a classic demonstration of alkali metal reactivity: 2Na + 2H₂O → 2NaOH + H₂. The sodium skates across the water surface as hydrogen gas is evolved, often melting into a ball from the heat of reaction. Adding phenolphthalein indicator to the water reveals the spreading pink color of NaOH as it forms. This reaction illustrates metallic bonding (soft metal), oxidation states, and the trend of increasing reactivity down Group 1.
Cảnh báo an toàn
- Sodium is highly reactive — NEVER handle with bare hands
- Keep sodium away from water until ready for demonstration
- Cut sodium on a dry tile; keep pieces small (pea-sized maximum)
- Use safety shield between reaction and audience
- Hydrogen gas is flammable — larger pieces may ignite the hydrogen
- NaOH solution formed is corrosive
- Never use pieces larger than a small pea for this demonstration
PPE cần thiết
Vật liệu
-
Sodium metal (1 small piece)Pea-sized, stored under mineral oil
-
Phenolphthalein indicator (5 mL)Added to water
-
Distilled water (500 mL)
-
Mineral oil (For storage)
Thiết bị
Quy trình
Fill the trough with about 300 mL of water. Add a few drops of phenolphthalein indicator. Set up the safety shield.
Using forceps, remove a small piece of sodium from the mineral oil. Blot excess oil with filter paper on a dry tile.
Cut a very small piece (no larger than a pea). Return the remainder to the mineral oil.
Drop the sodium piece into the water from behind the safety shield. Step back immediately.
Observe: the sodium floats, melts into a ball, darts across the surface, fizzes (H₂ evolution), and the water turns pink (NaOH + phenolphthalein).
After the reaction is complete, test the pH of the solution with pH paper (should be >12).
Discuss: Group 1 reactivity trend (Li < Na < K < Rb < Cs), the redox nature of the reaction, and why sodium floats (density 0.97 g/mL < 1.0 g/mL).
Kết quả dự kiến
The sodium piece fizzes vigorously on the water surface, darting around as hydrogen is released. It melts into a shiny ball. The phenolphthalein turns the water bright pink in a spreading pattern. With very small pieces, no flame occurs; slightly larger pieces may produce a yellow sodium flame.
Dọn dẹp
Neutralize the NaOH solution with dilute HCl before disposing down the drain. Ensure no unreacted sodium remains. Clean the trough thoroughly.
Chi tiết
- Danh mục
- Classroom Demonstrations
- Độ khó
- Advanced (University)
- Thời gian
- 25 phút
- Chi phí ước tính
- $12,00
- Số bước
- 7
- Vật liệu
- 4