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Metallurgy & Metal Processing Global Industrial Scale $15 billion

개요

Electroplating deposits a thin layer of metal onto a conductive substrate using electrolysis, providing corrosion protection, wear resistance, and decorative finish. The most common electroplating processes are zinc plating (corrosion protection for steel), nickel plating (decorative and functional), and chromium plating (hardness and aesthetics). The automotive, electronics, aerospace, and jewelry industries are major consumers. Decorative chrome plating on car bumpers and bathroom fixtures uses only 0.25-0.50 microns of chromium over 10-30 microns of nickel.

화학 공정

The workpiece is cleaned (alkaline soak clean, acid pickle, electrocleaning) and racked or placed in a barrel. It is immersed in a plating bath containing dissolved metal salt, complexing agents, brighteners, and levelers. DC current deposits metal ions as a coherent metal coating. For decorative chrome: a copper strike (1-2 microns), then nickel (10-30 microns from Watts bath), then chromium (0.25-0.50 microns from chromic acid bath). Bath composition and current density control deposit quality.

Ni²⁺ + 2e⁻ → Ni(s) (nickel cathodic deposition, Watts bath)
CrO₃ + 6H⁺ + 6e⁻ → Cr(s) + 3H₂O (chromium deposition from hexavalent chromium)
Zn²⁺ + 2e⁻ → Zn(s) (zinc plating for corrosion protection)

원자재

Nickel sulfate (NiSO₄) + nickel chloride (NiCl₂) — Nickel refining (Nickel plating bath (Watts bath: 250 g/L NiSO₄, 45 g/L NiCl₂, 35 g/L H₃BO₃))
Chromic acid (CrO₃) — Oxidation of Cr₂O₃ (Chromium plating bath (250 g/L CrO₃, 2.5 g/L H₂SO₄))
Zinc chloride or zinc sulfate — Zinc refining (Zinc plating bath)

최종 제품

Electroplated metal components — Automotive, electronics, aerospace, bathroom fixtures, jewelry (0.1-100+ micron coating thickness depending on application)

Environmental Impact

Hexavalent chromium (Cr(VI)) used in traditional chrome plating is a known carcinogen (IARC Group 1) and is heavily regulated under REACH, RoHS, and US EPA. Plating wastewater contains heavy metals requiring treatment by precipitation, ion exchange, or reverse osmosis. Drag-out losses from plating baths constitute the main waste source. Trivalent chromium plating is replacing hexavalent in many applications.

안전 고려사항

⚠ Hexavalent chromium is a carcinogen — strict exposure limit (5 ug/m³)
⚠ Nickel is a sensitizer and carcinogen (inhalation, IARC Group 1)
⚠ Acid mist from plating baths causes respiratory damage
⚠ Hydrogen gas evolution creates explosion risk in enclosed spaces

최근 혁신

Trivalent chromium (Cr(III)) plating eliminates carcinogenic hexavalent chromium.
PVD (physical vapor deposition) and CVD coatings provide chrome-like appearance without wet chemistry.
Pulse and pulse-reverse plating improves deposit quality and reduces waste.
Ionic liquid electrolytes enable electroplating at room temperature for reactive metals.