Iron(III) Hydroxide Precipitation
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FeCl3 + 3NaOH → Fe(OH)3↓ + 3NaCl
개요
Iron(III) chloride reacts with sodium hydroxide to form a rust-brown gelatinous precipitate of iron(III) hydroxide. Fe(OH)₃ has an extremely low Ksp of 2.8 × 10⁻³⁹, precipitating even at slightly acidic pH. The gelatinous nature makes it an excellent flocculant for water treatment.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Iron(III) Chloride FeCl₃ | 1 | (aq) |
| 반응물 | Sodium Hydroxide NaOH | 3 | (aq) |
| 생성물 | Sodium Chloride NaCl | 3 | (aq) |
일상 속 예시
The rust-colored sludge in water treatment plants is mainly iron(III) hydroxide precipitated by adding base to iron-rich water.
산업적 중요성
광산 폐수 및 산업 폐수의 철 이온 제거에 사용됩니다. 수산화철은 중금속 이온 흡착 능력이 있어 폐수 처리의 응집·침전 공정에 활용됩니다.
성질
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -88.0 kJ/mol