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과산화수소의 빠른 촉매 분해로 거대한 거품 기둥 생성
목표
아이오딘화칼륨을 이용한 과산화수소의 촉매 분해를 실증하고, 촉매 작용·발열 반응·기체 발생의 개념을 설명한다.
배경
Elephant toothpaste is one of the most popular chemistry demonstrations. Concentrated hydrogen peroxide (H₂O₂) is decomposed rapidly by a potassium iodide (KI) catalyst, releasing oxygen gas and steam. When performed in a narrow-neck flask with dish soap, the oxygen gas creates a towering column of foam that erupts like giant toothpaste. The reaction is exothermic, and the foam is warm to the touch. The iodide ion acts as a catalyst by cycling between I⁻ and IO⁻ intermediates.
안전 경고
- 30% H₂O₂ causes severe skin burns and eye damage
- Wear face shield and heavy-duty gloves
- Do not stand over the flask when adding KI
- The foam is hot — do not touch immediately
- Perform behind a safety shield
필수 개인 보호 장비
재료
-
Hydrogen peroxide (30%) (50 mL)30% concentration required for dramatic effect
-
Potassium iodide (KI) (10 g)Dissolved in 25 mL water
-
Liquid dish soap (15 mL)
-
Food coloring (5 drops)Optional, for visual effect
-
Large tray or bin (1)To catch overflow
장비
실험 절차
Place the Erlenmeyer flask on the large tray. Set up the safety shield.
Carefully pour 50 mL of 30% H₂O₂ into the flask.
Add 15 mL of dish soap and a few drops of food coloring. Swirl gently to mix.
Dissolve 10 g of KI in 25 mL of warm water. Pour this solution into the flask using a funnel and step back immediately.
Observe the rapid evolution of foam. The reaction is complete in seconds. Discuss the role of KI as a catalyst.
After the foam cools, students may touch it (with gloves). It contains only water, oxygen, soap, and KI — no H₂O₂ remains.
예상 결과
A dramatic eruption of warm, colored foam that rises 1–2 meters above the flask. Steam may be visible. The reaction demonstrates catalysis (KI is not consumed), exothermic processes, and gas evolution (O₂).
정리
The foam is non-toxic (soap, water, KI). Rinse down the drain with plenty of water. Clean the flask and tray.
세부 정보
- 난이도
- Beginner (Middle School)
- 소요 시간
- 20 분
- 예상 비용
- $10.00
- 단계
- 6
- 재료
- 5