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녹과 알루미늄에서 용융 철을 생성하는 극도의 발열 산화환원 반응
목표
알루미늄이 산화철을 용융 철로 환원하는 극단적인 발열 산화환원 반응을 실증한다.
배경
The thermite reaction (2Al + Fe₂O₃ → Al₂O₃ + 2Fe) is one of the most exothermic chemical reactions known. Aluminum reduces iron(III) oxide to produce molten iron and aluminum oxide, reaching temperatures above 2500°C. The reaction is driven by the much greater affinity of aluminum for oxygen compared to iron (the activity series in dramatic action). Thermite is used industrially for welding railroad tracks and cutting through steel.
안전 경고
- EXTREME CAUTION: Reaction produces temperatures above 2500°C
- Perform OUTDOORS ONLY with at least 10 m clearance
- Molten iron droplets are ejected — no one within 5 meters
- Heavy-duty safety shield is mandatory
- Have a Class D fire extinguisher on hand (not water or CO₂)
- Aluminum powder is an explosion hazard — keep away from flame until ready
- Never attempt to move or disturb the reaction once ignited
- Wait at least 30 minutes for products to cool before approaching
필수 개인 보호 장비
재료
-
Iron(III) oxide (Fe₂O₃) powder (50 g)Fine rust powder
-
Aluminum powder (15 g)Fine mesh (200+)
-
Magnesium ribbon (20 cm)Ignition fuse
-
Sand (5 kg)Insulation bed
장비
실험 절차
OUTDOORS ONLY: Set up the ring stand over the sand-filled bucket. Place the clay pot (with drainage hole plugged with a small wad of paper) on the iron ring.
Mix 50 g Fe₂O₃ with 15 g Al powder thoroughly (by weight, approximately 3:1 ratio) in the clay pot.
Insert the magnesium ribbon into the top of the mixture as a fuse. Ensure the shield is positioned correctly.
Ensure all observers are at least 5 meters away and behind cover. Light the magnesium ribbon with a long lighter and retreat immediately.
Observe from safe distance: the reaction produces an intensely bright white-orange glow and sparks. Molten iron drips through the pot into the sand below.
Wait at least 30 minutes for everything to cool. Dig through the sand to find the solidified iron button.
Examine the iron button and white Al₂O₃ slag. Discuss: activity series, enthalpy of formation, why Al is used in thermite (high affinity for O₂), and industrial applications.
예상 결과
An intensely bright, self-sustaining reaction lasting 10–20 seconds. Molten iron collects at the bottom (a solid metal button when cooled). White Al₂O₃ slag forms on top. The reaction demonstrates the extreme energy difference between Al-O and Fe-O bonds.
정리
Once fully cooled, collect the iron button and slag. Sand can be reused. Do not pour water on hot products. Dispose of residue in general waste.
세부 정보
- 난이도
- Advanced (University)
- 소요 시간
- 30 분
- 예상 비용
- $15.00
- 단계
- 7
- 재료
- 4