Calcium Sulfate Precipitation (Gypsum)
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Ca(NO3)2 + Na2SO4 → CaSO4↓ + 2NaNO3
개요
Calcium nitrate reacts with sodium sulfate to precipitate calcium sulfate (Ksp = 4.9 × 10⁻⁵). CaSO₄ is sparingly soluble, not truly insoluble. The dihydrate form (CaSO₄·2H₂O) is gypsum, one of the most important construction materials. Plaster of Paris is the hemihydrate form.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
| 생성물 | Calcium Sulfate CaSO₄ | 1 | (s) |
| 생성물 | Sodium Nitrate NaNO₃ | 2 | (aq) |
일상 속 예시
Drywall (gypsum board) used in nearly every building contains calcium sulfate dihydrate, produced by similar precipitation chemistry.
산업적 중요성
석고 생산량은 연간 2억 5천만 톤을 초과하며, 석고보드, 석고, 시멘트, 토양 개량제에 사용됩니다. 발전소의 배연탈황 석고가 점점 더 중요해지고 있습니다.
성질
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -8.0 kJ/mol