Chromium(III) Hydroxide Precipitation
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CrCl3 + 3NaOH → Cr(OH)3↓ + 3NaCl
개요
Chromium(III) chloride reacts with sodium hydroxide to form a green gelatinous precipitate of chromium(III) hydroxide (Ksp = 6.3 × 10⁻³¹). Cr(OH)₃ is amphoteric, dissolving in both excess acid and excess NaOH. In excess NaOH, it forms the green chromite ion [Cr(OH)₄]⁻.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Sodium Hydroxide NaOH | 3 | (aq) |
| 생성물 | Sodium Chloride NaCl | 3 | (aq) |
일상 속 예시
The green color of some gemstones like emerald is due to chromium(III) ions, the same oxidation state that produces this green precipitate.
산업적 중요성
수산화크롬(III) 침전은 특히 크롬 도금과 가죽 무두질 폐수에서 크롬을 제거하는 산업 폐수 처리에 사용됩니다.
성질
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -90.0 kJ/mol