Copper Sulfide Precipitation
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CuSO4 + Na2S → CuS↓ + Na2SO4
개요
Copper sulfate reacts with sodium sulfide to form a black precipitate of copper(II) sulfide (Ksp = 1.3 × 10⁻³⁶). CuS is one of the most insoluble compounds known. The jet-black precipitate forms instantly and is used to identify Cu²⁺ ions in systematic qualitative analysis.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Copper(II) Sulfate CuSO₄ | 1 | (aq) |
| 생성물 | Sodium Sulfate Na₂SO₄ | 1 | (aq) |
일상 속 예시
The black tarnish on copper pots exposed to sulfur-containing foods (eggs, garlic) is related to copper sulfide formation.
산업적 중요성
황화물 침전은 중금속 제거를 위한 광산 폐수 처리에 사용됩니다. CuS(방연석)은 또한 자연적으로 발생하는 구리 광석 광물이기도 합니다.
성질
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -84.0 kJ/mol