Electrorefining of Copper
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Cu (impure) → Cu2+ + 2e− → Cu (pure)
개요
Impure copper anodes (99.5%) dissolve electrochemically while pure copper (99.99%) deposits at the cathode from CuSO₄/H₂SO₄ electrolyte. Impurities either remain in solution or fall as anode slime (containing gold, silver, platinum). The voltage required is only 0.2–0.3 V since the same reaction occurs at both electrodes.
참여 물질
일상 속 예시
All the copper wiring in your home was refined to 99.99% purity by this electrorefining process.
산업적 중요성
전기·전자 산업에 필요한 고순도 구리 생산의 표준 공정입니다. 양극 슬라임에서 금, 은 등 귀금속을 회수하는 부가 가치도 있습니다.
성질
- 가역 반응
- 아니오
- 에너지
- 흡열
- ΔH
- 0.0 kJ/mol