Galvanic Corrosion of Zinc (Sacrificial Anode)
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Zn → Zn2+ + 2e−
개요
Zinc acts as a sacrificial anode when electrically connected to iron or steel, preferentially oxidizing to protect the less reactive metal. Zinc's standard reduction potential (-0.76 V) is more negative than iron's (-0.44 V), so zinc corrodes first. This is the principle of cathodic protection and galvanization.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Zinc Zn | 1 | (s) |
일상 속 예시
Galvanized steel roofing, fencing, and car bodies are coated with zinc that corrodes preferentially, protecting the steel underneath.
산업적 중요성
선박, 해양 구조물, 매설 배관, 저수탱크의 전기화학적 방식(부식 방지)에 널리 사용됩니다. 용융 아연 도금(갈바나이징)도 같은 원리로 철강을 보호합니다.
성질
- 유형
- Redox
- 가역 반응
- 아니오
- 에너지
- 발열