Hydrogen Peroxide Disproportionation
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2H2O2 → 2H2O + O2
개요
Hydrogen peroxide simultaneously acts as both oxidizing and reducing agent in this disproportionation reaction. One molecule is reduced to water (O goes from -1 to -2) while another is oxidized to oxygen gas (O goes from -1 to 0). Manganese dioxide or the enzyme catalase dramatically accelerate this reaction.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Hydrogen Peroxide H₂O₂ | 2 | (aq) |
| 생성물 | Oxygen O | 1 | (g) |
| 생성물 | Water H₂O | 2 | (l) |
일상 속 예시
The fizzing when hydrogen peroxide is applied to a wound occurs because catalase enzyme in blood rapidly decomposes H₂O₂, releasing oxygen bubbles.
산업적 중요성
산소 발생 반응을 이용한 공업적 산소 생산, 잠수함 비상 산소 공급, 로켓 추진제(고농도 H₂O₂)에 활용됩니다. 하수 처리의 탈산소화에도 응용됩니다.
성질
- 유형
- Redox
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -196.1 kJ/mol
- 촉매
- MnO₂ or catalase enzyme