Hydrogen Sulfide Oxidation by Chlorine
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H2S + Cl2 → 2HCl + S
개요
Chlorine oxidizes hydrogen sulfide to elemental sulfur while being reduced to hydrochloric acid. Sulfur is oxidized from -2 to 0. This reaction is used in removing hydrogen sulfide from natural gas (sweetening) and in treating hydrogen sulfide-containing wastewater.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Hydrogen Sulfide H₂S | 1 | (g) |
| 반응물 | Chlorine Cl | 1 | (g) |
| 생성물 | Sulfur S | 1 | (s) |
| 생성물 | Hydrochloric Acid HCl | 2 | (g) |
일상 속 예시
The rotten egg smell of hydrogen sulfide from sewers can be eliminated by chlorination, which oxidizes H₂S to odorless elemental sulfur.
산업적 중요성
석유 정제 공장의 황화수소 폐가스 처리에 활용됩니다. 원소 황 회수 및 석유 정제의 탈황 공정(클라우스 공정)과 관련된 산업적 반응입니다.
성질
- 유형
- Redox
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -186.0 kJ/mol