Methane Partial Oxidation (Steam Reforming)
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CH4 + H2O → CO + 3H2
개요
Methane reacts with steam over a nickel catalyst to produce synthesis gas (syngas), a mixture of carbon monoxide and hydrogen. Carbon is oxidized from -4 to +2 while hydrogen in water is reduced from +1 to 0. This highly endothermic reaction is performed at 700-1100 C and 15-30 atm.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Methane CH₄ | 1 | (g) |
| 반응물 | Water H₂O | 1 | (g) |
| 생성물 | Carbon Monoxide CO | 1 | (g) |
| 생성물 | Hydrogen H | 3 | (g) |
일상 속 예시
Over 95% of the world's hydrogen is produced by this reaction, supplying hydrogen for ammonia production that feeds half the world's population.
산업적 중요성
전 세계 수소 생산의 약 95%가 천연가스 수증기 개질(SMR)로 이루어집니다. 암모니아 합성(하버 공정), 메탄올 합성, 피셔-트롭쉬 합성의 수소 및 합성가스 공급원입니다.
성질
- 유형
- Redox
- 가역 반응
- 예
- 에너지
- 흡열
- ΔH
- 206.0 kJ/mol
- 촉매
- Nickel on alumina