냉찜질 팩의 화학 원리
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질산암모늄의 흡열 용해 연구하기
목표
질산암모늄이 물에 용해될 때의 온도 변화를 측정하여 즉석 냉찜질 팩에 사용되는 흡열 용해 과정을 실증한다.
배경
Ammonium nitrate dissolves endothermically in water, absorbing heat from the surroundings and causing a significant temperature drop. This principle is used in commercial instant cold packs for first aid. The dissolution has ΔH = +25.7 kJ/mol.
안전 경고
- Ammonium nitrate is an oxidizer — keep away from organic materials and heat
- Do not mix with anything other than water for this experiment
- Wear goggles
필수 개인 보호 장비
재료
-
Ammonium nitrate (NH₄NO₃) (30 g)Or from a commercial cold pack
-
Distilled water (100 mL)Room temperature
장비
실험 절차
Add 100 mL of distilled water to the polystyrene cup calorimeter. Record the initial temperature.
Weigh 30 g of ammonium nitrate.
Add the ammonium nitrate to the water. Stir gently to dissolve.
Record the temperature every 30 seconds as it drops. Note the minimum temperature.
Feel the outside of the cup — it should feel cold.
Calculate ΔH of dissolution per mole: q = mcΔT, n = mass/M(NH₄NO₃), ΔH = q/n.
예상 결과
Temperature should drop 15-20°C. 30 g NH₄NO₃ = 0.375 mol. q = 100 × 4.18 × ΔT. Calculated ΔH should be approximately +25 kJ/mol (±15%).
정리
The ammonium nitrate solution is safe to dispose down the drain (dilute). Rinse the calorimeter.
세부 정보
- 카테고리
- Thermochemistry
- 난이도
- Beginner (Middle School)
- 소요 시간
- 20 분
- 예상 비용
- $6.00
- 단계
- 6
- 재료
- 2