Aqua Regia Dissolving Gold
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Au + 3HCl + HNO3 → HAuCl4 + NO + 2H2O
개요
Aqua regia (3:1 mixture of HCl and HNO₃) dissolves gold, which is inert to either acid alone. Nitric acid oxidizes gold to Au³⁺ while hydrochloric acid provides chloride ions that stabilize the gold as [AuCl₄]⁻ complex. The synergy between the two acids makes aqua regia effective against noble metals.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Gold Au | 1 | (s) |
| 반응물 | Nitric Acid HNO₃ | 1 | (aq) |
| 반응물 | Hydrochloric Acid HCl | 3 | (aq) |
| 생성물 | Water H₂O | 2 | (l) |
일상 속 예시
During WWII, George de Hevesy dissolved the Nobel Prize gold medals of Max von Laue and James Franck in aqua regia to hide them from the Nazis.
산업적 중요성
왕수는 금 정련, 귀금속 용해를 위한 분석화학, 그리고 전자 폐기물에서 귀금속을 회수하는 데 사용됩니다.
성질
- 유형
- Redox
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -150.0 kJ/mol