Saponification (Fat + NaOH)
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fat + 3NaOH → glycerol + 3 sodium carboxylate (soap)
개요
Saponification is the base-catalyzed hydrolysis of triglyceride fats or oils by sodium hydroxide to produce glycerol and sodium salts of fatty acids (soap). Unlike acid-catalyzed ester hydrolysis, saponification is irreversible because the carboxylate salt is deprotonated. The reaction requires heating and stirring.
참여 물질
| 역할 | 물질 | 계수 | 상태 |
|---|---|---|---|
| 반응물 | Sodium Hydroxide NaOH | 3 | (aq) |
| 생성물 | Glycerol C₃H₈O₃ | 1 | (l) |
일상 속 예시
Handmade soap is produced by heating vegetable oils or animal fats with lye (NaOH) in this ancient saponification reaction.
산업적 중요성
세계 비누 산업은 연간 2,500만 톤 이상을 생산합니다. 부산물인 글리세롤은 의약품, 화장품, 식품 가공에 사용됩니다.
성질
- 유형
- Organic
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -25.0 kJ/mol