Polymerization of Vinyl Chloride to PVC
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nCH2=CHCl → (–CH2–CHCl–)n
개요
Vinyl chloride monomer (VCM) undergoes free radical addition polymerization to form polyvinyl chloride (PVC), the third most produced plastic worldwide. PVC is rigid by default but can be made flexible with plasticizers. Suspension polymerization is the most common industrial method.
일상 속 예시
PVC pipes, vinyl flooring, window frames, wire insulation, and credit cards are all made from this polymerization reaction.
산업적 중요성
건설, 의료, 자동차, 포장 용도로 연간 4,500만 톤 이상의 PVC가 생산됩니다.
성질
- 유형
- Organic
- 가역 반응
- 아니오
- 에너지
- 발열
- ΔH
- -72.0 kJ/mol
- 촉매
- Free radical initiators
관련 반응
Epoxidation of Alkenes (mCPBA)
Swern Oxidation
Oxidation of Secondary Alcohol to Ketone
E2 Elimination (Dehydrohalogenation)
Claisen Condensation (Ethyl Acetate)
Aldol Condensation of Acetaldehyde
Kolbe Electrolysis
Baeyer-Villiger Oxidation
Beckmann Rearrangement (Cyclohexanone Oxime)
Dehydration of Ethanol
Frequently Asked Questions
What is the equation for Polymerization of Vinyl Chloride to PVC?
The balanced equation is: nCH₂=CHCl → (–CH₂–CHCl–)ₙ.
What type of reaction is Polymerization of Vinyl Chloride to PVC?
Polymerization of Vinyl Chloride to PVC is a organic reaction.
Is Polymerization of Vinyl Chloride to PVC exothermic or endothermic?
Polymerization of Vinyl Chloride to PVC is exothermic (releases energy). The enthalpy change (ΔH) is -72.0 kJ/mol.
What conditions are needed for Polymerization of Vinyl Chloride to PVC?
This reaction requires a catalyst (Free radical initiators).