Barium Hydroxide and Ammonium Thiocyanate (Endothermic)
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Ba(OH)2·8H2O + 2NH4SCN → Ba(SCN)2 + 2NH3 + 10H2O
개요
This highly endothermic acid-base reaction absorbs so much heat that it can freeze water beneath the flask. Mixing barium hydroxide octahydrate with ammonium thiocyanate drops the temperature below -20 C. The ammonium ion acts as a weak acid donating protons to hydroxide.
참여 물질
일상 속 예시
This is one of the most dramatic endothermic reaction demonstrations, where a wet board freezes to a beaker as the reaction proceeds.
산업적 중요성
이 반응은 주로 흡열 과정과 엔트로피 주도 반응의 교육용 시연에 사용되며, ΔG = ΔH - TΔS라는 열역학 개념을 설명합니다.
성질
- 유형
- Acid-Base
- 가역 반응
- 아니오
- 에너지
- 흡열
- ΔH
- 170.0 kJ/mol