Photocatalytic Water Splitting (TiO₂)
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2H2O → 2H2 + O2
Descripción general
Titanium dioxide absorbs UV light and generates electron-hole pairs that can split water into hydrogen and oxygen. Discovered by Fujishima and Honda in 1972, this reaction is the basis of artificial photosynthesis research. The bandgap of TiO₂ (3.2 eV) limits absorption to UV, so researchers are developing visible-light photocatalysts.
Participantes
| Rol | Sustancia | Coeficiente | Estado |
|---|---|---|---|
| Reactivo | Water H₂O | 2 | (l) |
Ejemplo cotidiano
Self-cleaning glass windows are coated with TiO₂ that photocatalytically decomposes organic dirt when exposed to sunlight.
Importancia industrial
Área de investigación clave para la producción de hidrógeno solar limpio en la economía del hidrógeno.
Propiedades
- Tipo
- Photochemical
- Reversible
- No
- Energía
- Endotérmico
- ΔH
- 572,0 kJ/mol
- Catalizador
- TiO₂ (titanium dioxide)